Browsing by Subject "Free radical reactions"
Now showing items 1-5 of 5
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A degradable atom transfer radical polymerization inimer: Synthesis, polymerization, and cleavage of the resulting polymer products
(2017)A novel degradable inimer for atom transfer radical polymerization (ATRP), 2-(6-(2-((2-bromo-2-methylpropanoyl)oxy)ethyl)pyridin-2-yl)ethyl methacrylate (PyDEBrMΑ), was synthesized by the two-step esterification of ...
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Article
End-linked, amphiphilic, degradable polymer conetworks: Synthesis by sequential atom transfer radical polymerization using a bifunctional, cleavable initiator
(2012)End-linked, degradable, amphiphilic polymer conetworks (APCNs) of various compositions and architectures were synthesized by sequential atom transfer radical terpolymerization of monomers and cross-linker using a cleavable, ...
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Symmetrical polymer systems prepared using a degradable bifunctional atom transfer radical polymerization initiator: Synthesis, characterization, and cleavage
(2017)Linear (co)polymers and dimethacrylate-end-linked polymer networks of methyl methacrylate with 2-(dimethylamino)ethyl methacrylate, cleavable in the middle of the polymer chain, either under thermolysis or alkaline hydrolysis ...
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Synthesis, characterization and thermolysis of hyperbranched homo- and amphiphilic Co-polymers prepared using an inimer bearing a thermolyzable acylal group
(2012)Degradable hyperbranched polymers were synthesized via self-condensing atom transfer radical copolymerization of methyl methacrylate (MMA) with a novel inimer bearing a thermolyzable acylal group. This inimer was ...
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Article
Thermal conductivity and degradation behavior of HDPE/graphene nanocomposites: Pyrolysis, kinetics and mechanism
(2017)Graphene-filled high-density polyethylene nanocomposites varying filler’s size (5, 10 and 25 × 10−6 m in diameter) were prepared by the melt-mixing method, and their thermal properties are then investigated by TG, Py–GC/MS ...